Applications
The
PVC structure allows it to be mixed (compounded) with all different "additives".
By varying the tin stabilizer all properties can be obtained in the final
product.
Rigid
(transparent) films and sheets (calendering).
This
is by far the largest application for organotin stabilizers in Europe.
The processing technique is called calendering. Food contact approved
tin mercaptides are used to produce rigid transparent PVC films and sheets
which are mainly used for food packaging and for pharmaceutical applications
(blisters).
This application represents approximately 50 percent of the total consumption
of organotin stabilizers in Europe due to the unique property of organotin
stabilizers to provide transparency to PVC with almost no discoloration.
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Rigid PVC bottles (injection blow molding).
Rigid PVC bottles are produced by (injection) blow molding. Under the
high shear during processing by this application technique, organotin
mercaptides are efficient PVC stabilizers due to very good heat stability
and lubricating effect.
The bottles are mainly used for vegetable oil, juices, wine or non-food
packaging (cosmetics, etc.). Since food approval is generally required,
octyltin- and methyltin mercaptides are used. [Back to Top]
Weatherable transparent sheets (extrusion)
These products are used in the construction industry mainly for roofing,
and, therefore, require very good transparency, clarity and UV outdoor
weathering stability.
For this application mainly butyltin stabilizers and methyltin are used.
Because of the weatherability requirements, most stabilizers are based
on carboxylates (or sometimes mixtures of carboxylates and mercaptides).
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Pipes and fittings (extrusion and injection molding).
Organotin stabilizers (mainly octyltin and methyltin) are used for rigid
PVC potable water pipes and fittings in countries where lead stabilizers
are not allowed for regulatory reasons.
The regulations in France, Germany, and The Netherlands, covering potable
water pipes, approve both thioglycolate and reverse ester products, while
in Italy only thioglycolates are allowed. [Back to Top]
Profiles and sidings.
Organotin stabilizers (mainly butyltin) are used for rigid PVC profiles
and sidings. Venetian blinds, rain gutters, window profiles and, in particular
in the U.S. sidings, are successful applications for indoor and outdoor
use.
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Miscellaneous.
Other applications do exist for both rigid and flexible PVC: rigid PVC
foams, top coat layers in flexible PVC flooring, flexible calendered sheets,
and various rigid profiles are just some examples.
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